"From the producer-director of Charlie's Angels comes this one-hour action-comedy about a computer nerd in a quarter-life crisis. When Chuck Bartowski (Zachary Levi) opens a surprising e-mail, he unwittingly downloads an entire server of government secrets into his brain and turns accidental super spy. Immediately, Chuck becomes the target of two secret operatives, hard-case NSA agent Casey (Adam Baldwin) and sexy CIA agent Sarah (Yvonne Strahovski). When the smoke clears, the three join forces to protect the world. But Chuck has to keep it a secret from his family and friends, including unsuspecting coworker Morgan (Joshua Gomez), beautiful and upbeat sister Ellie Bartowski (Sarah Lancaster) and her perfect boyfriend Devon, a.k.a. "Captain Awesome" (Ryan McPartlin). Now the fate of the world lies in Chuck's hands as he embarks on his first missions filled with espionage, double agents and . . . a nerd." -- iTunes Store
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When Chuck Bartowski (series star Zachary Levi) opens an e-mail subliminally encoded with government secrets, he unwittingly downloads an entire server of sensitive data into his brain. Now, the fate of the world lies in the unlikely hands of a guy who works at a Buy More Electronics store with his best buddy, Morgan Grimes (series star Joshua Gomez), and who lives with his ever-supportive sister, Ellie (series star Sarah Lancaster). Instead of fighting computer viruses, Chuck must now confront assassins and international terrorists. With the government's most precious secrets in Chuck's head, Major John Casey (series star Adam Baldwin) of the National Security Agency assumes the responsibility of protecting him. His partner is the CIA's top agent -- and Chuck's first date in years -- Sarah Walker (series star Yvonne Strahovski). They'll try to keep him safe when he trades his pocket protector for a bulletproof vest.
the fine print: Downloads posted on the Free iTunes Downloads blog are usually free for ~1 week. After that, you'll have to pay for them.